Timeoff,
Are you asking about applying a teflon or other lubricant to the leading edge of an unprotected wing (ie, one with no ice protection such as boots, heat, fluid, etc), or are you talking about applying silicon to the leading edge of a protected wing?
I suspect where you're going with that is finding something to coat the leading edge upon which ice will not stick. Many pilot erroneously believe that by spraying their boots or the leading edge of their wing with an oily substance, the ice won't stick...but it will. Paint it with a teflon or other similiar type paint or coating, and it's still going to stick. Or form, which is a better way of putting it.
Some wings leak fluid out of very small pores; this is the basis of the TKS system. It's effective, until one is of fluid, to a point. Others use methanol for various surfaces from the nose of a jet to propellers. These prevent freezing precipitation from bonding to the surface not so much by producing a slick liquid surface that causes the moisture to slide away, as creating a consistantly melting boundary upon which the freezing precip can find no purchase.
Something like silicon or teflon soloutions in a liquid form merely slough off. In a solid form such asa coating (imagine your frypan, but on the leading edge of the wing), pecipitation will still bond. Something is needed to either break it free mechanically (such as in inflatable boot), or melt/weaken the ice closest to the surface (fluid, heat, etc).
Some pilots believe that by spraying their boots with various substances, they can prevent ice adhesion. This may work with trace icing, but not with moderate or severe icing. Part of the reason is that coatings tend to change propeties in the presence of the cold slipstream, and part of it is that the coating inevitably gets removed to some degree or another by the slipstream. But the main reason that it doesn't work is the very definition of severe icing...icing which can't be removed fast enough by the onboard anti-icing or de-icing equipment...it accumulates faster than it can be removed. This definition is subjective to the individual aircraft and system...what is light to moderate icing for one aircraft may be severe to another.
Coating your wings with pledge or various oils doesn't prevent ice. Goodyear and other companies make boot treatments which are often mistaken for soloutions to prevent icing...they're not. Those soloutions are intended to extend boot life by treating the rubber, and a number of soloutions that pilots might unwittingly apply do just the oppsite...contribute to boot deterioration.
A much better idea is to come to the icing table armed first with the necessary equipment, and a close second with both the knowledge and judgement to properly use it. A number of different innovative ideas have been used over the years from conventional inflatable rubber boots to ultraonic devics intnded to break up and remove ice. Magnetic devices, heated blankets, hot air from various engine sources ("bleed air"), etc, are all in use, or have been tried.
Icing itself is very dependent on temperature, dewpoint, droplet size and condition, airspeed, the shape of the wing, angle of attack, etc. Icing can be very unpredictable. Icing can occur suddently without being forecast, in areas where no icing is being reported, in freezing conditions, in the summer, in the winter, in the mountains and by the sea. The first word is caution and the second is suspicion when dealing with ice. Trace ice can quickly become severe. A few days ago I went from trace to two inches of ice in very short order in very mild convective activity in the desert in a very arid area of the middle east. Who'da thunk it? Yesterday we encountered a lot of supercooled water under freezing conditions, and rapid ice buildup that surprised even some very experienced weather experts observing what occured. If they're surprised, you can bet I couldn't have predicted it.
I'm not nearly so educated on such things...being lowly aviator. My approach is a whole lot more simple. I assume that it can occur under the most unexpected conditions, and as a result, it's seldom surprising...expect it, plan for it, and plan to avoid it where ever you can. Ice is a whole lot easier to handle when you aren't in it, becuse you've planned your way around it, than trying to figure out how to get rid of the stuff. Even with teflon and a barrel of alcohol.