I dont think its a good idea if I tell them "hey, just so ya know there is no way I'm gonna move b/c my wife makes too good of money at her job." Now, I wouldn't mind flying outta DCA or IAH where the commute wouldn't be all that bad.
As far as being able to handle PIC quickly, it shouldn't be too much of a problem. Part of the reason I want to leave my current job is because I will never see captain. (we only have 6 aircraft) Not to mention, no medical, dental, 401, or really any benifits at all whatsoever. (Legitimate gripe)
In my opinion, Colgan seems like a decent place to work. Quick upgrade, 2 crew environment and turboprops. I'm used to flying 2 crew and I work for a 121 operation.