It's really not that confusing. A certificate holder cannot simply comply with the duty, flight, and rest regulations of Part 135 for 14 hours, then move to Part 91 with no restrictions. It doesn't work like that. The certificate holder doesn't simply keep on trucking under Part 91 when all the duty and flight time has been used up.
By enjoying the privileges accorded the certificate holder, once the certificate holder has made the assignments (which must comply with 135), he or she can't assign beyond those restrictions, and the crew can't accept such an assignment.
By enjoying the privileges accorded the certificate holder, once the certificate holder has made the assignments (which must comply with 135), he or she can't assign beyond those restrictions, and the crew can't accept such an assignment.