There are a lot of factors here.
Let the wind be your guide. If the higher you go the faster the tailwind, then climb like a bat out of hell to get up there and take advantage of it as soon as you can. Then decend by dropping like a rock at the last minute. If you have a big headwind at the cruise altitude, then make it a nice cruise climb...no need to get up there quickly. Start your decent early by pushing the nose over with the power up and decend on the barber pole.
Ok, so don't fly like a bat or a rock, keep it comfortable for your passengers. I'm sure they'd rather fly for 25 minutes in smooth comfort versus 23 minutes of fighter pilot flying.
Where you will really save time is on departure and approach. I've seen a lot of pilots slow down way too early, or fly B-52 patterns. That kind of stuff will eat up minutes fast. Land with a slight tailwind (less than 10 knots) if you can do a straight-in versus a full traffic pattern. Take a visual when ever possible. Go as fast as you can as long as you can (keep in mind safety and pax comfort). This will save you a lot of time.
We figure every minute in the air costs us $12 in the Citation. Might not sound like much, but if you can save 2 minutes every flight, and fly 300 flights per year, that adds up to $7200! I fly a Citation I and we routinely beat the block times of a Citation II in our charter fleet flying the same trips, and I think its how we fly versus how they fly.
I am not recommending you sacrifice safety. But a King Air or a light Biz Jet can be flown very safely at its limits. If you are new to the airplane, take your time and get comfortable first. When the weather is Crap, sloooooow down, and take whatever time you need to be safe. But if it's VFR and it usually is, get the plane on the ground as quick as you can.
Good Luck,
JetPilot500