There is a difference between an electrically heated NESA type winshield made of glass, and a plastic windshield such as found on the Learjet. The glass windshield won't melt or distort from the heat, but the learjet windscreen certainly will.
(That's not entirely true: I have seen a thermal runaway on a NESA pan which did indeed melt it).
The learjet can be ruined in short order by too much heat. Additionaly, the Lear has no airspeed limitations related to heat. The Lear has a thck, multi layer (three layer) pliable windscreen that is highly impact resistant, and the angle at which it meets the relative wind provides a greater opprotunity for deflection than the windows on the DC-9.
The winshield heat on the 20 series lears also doubles as the emergency pressurization system. When acting as windshield heat, air is ducted outside and flows over two narrow columns on the windscreen. When directed as defog, it's inside, and can act as emergency pressurization.
Very different systems. Generally windshield heat is not used except for icing conditions, and descent. It should always be turned off on the ground, and auto shouldn't be used on the ground (or at all, if possible) due to the potential for windscreen damage. It only takes a failure of the high limit thermoswitch to cause permenant damage to the windscreen.