I'll look for it, but it has been awhile.
It has nothing to do with with safety, but it is relevant to terps descent gradient criteria. You are correct; every radial closer to the actual inbound course is easier, if not necessarily safer.
Here is the FAA reasoning: If you are inbound on an airway, there is a published MEA. It is therefore possible to calculate the descent required from the MEA to the intermediate segment altitude and divide by the intermediate segment distance to get gradient. For intermediate segments, 150ft/nm is around optimum, with 318ft/nm being maximum.
If you are arriving on any other radial, it is assumed that there is no no published MEA. (Yes, I know that one degree makes no practical difference, but that is not the way the red-tape makers think.)
Since there is no published MEA, it is impossible to calculate the descent required on the intermediate segment, and therefore you can't authorize that as a NoPT route, since terps requires that all segments have a calculated gradient. Purely legalese.
Now, you might then remark: " But what if I was on the airway at 9000ft? What about that descent gradient NOW?! You would be correct of course. But as always, the line had to be drawn somewhere, and it was not necessarily drawn in the most logical place.
Personally, I think it should be authorized to go stright-in from anywhere in the sector, but the feds never ask me for my blessing on these matters.