A/C with hot wings are typically jet aircraft. They use bleed air (before combustion) to heat the leading edges of the wings. This air hasn't yet been burned, but is very hot from the various stages of compression. It works pretty well, though it exacts a pretty heavy toll on performance as you rob the engine of that air they need to make thrust. There are a couple of exceptions to the hot surface. I know the older Lears use heated pads on the horizontal stab to deice that surface. I think the CitationJet may as well.
The next form of inflight deice/anti-ice is the inflatable boot. It is typically found on prop a/c including turboprops. The boot inflates, the ice cracks off. Pretty simple concept. We still do have some heated surfaces though, like the props, windshields, pitot static, etc. Those are electric.
The last common form is TKS deice/anti-ice. TKS fluid is pumped through a very fine mesh on the leading edge of the protected surface (like the wing) and removes any ice buildup while preventing further accretion. TKS fluid is unheated, and I believe is similar to the glycol we use to clean the a/c of snow and ice before taking off. It is relativly uncommon to find. The most common installations are on Hawker bizjets. You can also get Mooneys now with TKS systems. There are also several retrofits that add TKS systems to older a/c such as the Bonanza and Twin Commander 500's.
Ground deicing is conducted using heated glycol/water mix (usually 50/50.) This is known as type I fluid, and is used to remove accumulations of snow and ice. In conditions of falling frozen precip, usually a second fluid, either type II or IV are applied. These are applied full strength and cold. They help prevent futher accretion of snow and ice on the airframe until you can get airborne. They only work for a short period of time though, depending on the type of precip and the amount you are getting. This time is called a hold-over time and is established using charts we carry. Type IV generally has a longer hold-over time than Type II and is the most common used in air-carrier ops. All of thse fluids are VERY expensive, making their use by small a/c rare. Typical small operators (private stuff) choose to wait out the weather.